Thermal conductivity in liquid nitrogen pipes

29 April 2022

By: howard chan

Thermal Conductivity Kt 

The transfer of liquid nitrogen LN2 over any distance in a plant, whether indoors or outdoors will incurr significant economic loss of cryogen through evaporation and quality degradation of the cryogen delivered at the point of use. Under normal operational circumstances, the liquid in the system is constantly vaporizing into gaseous nitrogen due to constant heat leak.  The amount heat leaks depends on the type of insulation method used and the difference can be as big as 50X. Therefore, plant facility engineer need to understand thermal conductivity value Kof each insulation method during engineering evaluation before making  purchase decision. In this article we will share some calculation example for Kt value in foam insulated pipe and vacuum insulated pipe.

Traditional Foam Insulated Transfer Piping

For  decades,  the  accepted  method  of  insulating  cryogenic  transfer  pipe  (typically copper or schedule 10s stainless steel pipe) was to use foam insulation covered by a protective polyvinyl chloride layer. This  type  of  insulation is  inexpensive  and  works  well  when  new,  providing  typical heat   transfer   rates   above   10 - 20  Watt/meter (BTU/hr/ft )  at   LN2   temperatures.   However,   its performance  deteriorate  rapidly  within  five  years,  and  becomes  less  effective  in preventing vaporization of the liquid as the product ages.

If you are using liquid nitrogen (LN2)  in your processing operation and your transfer lines are more than 5 years old, you might be losing money every day. You probably see ice spot or frost along the pipeline and a water puddle  on  the  floor, but it won’t alarm  you  that  something  is  amiss. Instead,  what  typically  happens  is  that  you  will  gradually  use  more  and  more  LN2 with each passing year without even realizing.

The following theoretical model has been developed (Bootes & Hoogendoorn 1987) to predict the thermal conductivity of closed cell foams:

Vacuum Jacketed Piping

The technology in transfer piping for LN2  and other cryogenic fluids has made substantial advances since the early 1990s. Not only are today’s transfer lines better insulated to minimize the loss of LN2 through evaporation, but they are also easier to install and are virtually maintenance-free.

Two types of vacuum jacketed piping (VJP) systems (also referred to as vacuum insulated)  —  rigid  and  flexible  —  are  available  for  process  plant  installations where long runs of piping are required to transfer LN2  from a bulk storage vessel at the back of the plant to one or several use points.

 

There are three modes of heat transfer:

Conduction - CSM VJP reduces conduction by using low conductivity radial supports to prevent the inner pipe from touching the outer pipe

Convection - is prevented by removing the gas molecules from the space between the inner and the outer pipe at high vacuum 10-5Torr

Radiation - the inner pipe is wrapped with multiple layers of reflective radiation shield and low conductive spacer material to reduce radiation.

Vacuum jacketed pipes are designed to overcome the above heat leaks, as diagram below shown.

The  inner  pipe  which  carries  the  cryogenic  liquid  is wrapped   with   multiple   layers   of   super-insulation material, consisting of alternating layers of radiant heat barrier material  and  non-conductive  spacer  material.  Also, the   vacuum   annulus   contains   getter   materials   to absorb gas molecules to further improve the vacuum. Most importantly, the space between the two lines is evacuated and then sealed in a static vacuum system or by a on-site vacuum pump in dynamic vacuum system.

Conclusion

Thermal conductivity Kvalue for in super insulation vacuum jacketed pipe is 50 times lesser compared to foam insulation.

Read more in the blog: super insulation

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